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	» email contents alert » top accessed articles » article request » access registration » open access articles »  » list of issues »	» submit a manuscript » submission guidelines » open access option » editorial board » author information		Web Release Date: April 28, 2012 466 Collective Interactions of Molecules with an Interfacial Solid Katsumi Kaneko, Tsutomu Itoh, and Toshihiko Fujimori   [ Full Text PDF(J-STAGE)]  Open Access Article Molecules in nanoscale pores of the interfacial solid such as single wall carbon nanotube of which all component carbon atoms are exposed to the interfaces with gas phase show collective behavior, depending on the nanostructure. Confinement of molecules in nanoscale pores leads to stabilization of low-temperature phase and superhigh-pressure effect. Water molecules are adapted to hydrophobic nanopore spaces through cluster formation. The quantum fluctuation of H2 and D2 gives rise to a marked quantum molecular sieving effect. The Cu-based porous coordination polymer crystals can aspire CO2 repeatedly without the collapse of the crystal lattice.
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